Which leads to rate limiting S N bond breaking producing the

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The S niti osothiols were thought to be bidentately bound about the Cu(^2+). Which leads to rate limiting S N bond breaking producing the thiyl radical and nitiic oxide. A similar reaction was found to occur between S nitrosothiols and Cu+ and Fe2+ ions, but no other transition metals appeared to catalyse nitiic oxide formation from S nitrosothiols.

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